I have worked with a small amount of Corian. It works fine with normal carbide woodworking tooling.
I don't like polished surfaces so I did a matt finish.
Use the ROS up through 400.
Then cut square of white ScotchBrite and used that with the ROS and some paste wax.
http://www.naturalhandyman.com/iip/infcountertop/infsolidsurface.shtm
While DuPont does sell pieces large enough for a counter top to DIY they will allow small pieces to be sold and have a booklet on how to work it.
You can get it here.
http://stonewood.safeshopper.com/13/cat13.htm?500
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