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Cut out the grout with a grout saw.You can find them at any home improvement store. A razor knife might also work if the grout is weak enough.
Put a wide flat chisel as far under the tile and as flat against the floor as you can. Then begin slowly tapping with a hammer getting a little harder as you need to. It will either pop off the floor in one piece or it's going to snap.
This may not be salvagble.
Where's the water coming from?

removing tile