I did this on a pool in the past. The grout is a mixture of some acrylic floor wax (like Future™), Elmer's white glue, water and grout. This is a "secret mixture" used in the pool industry. If I remember correctly the mixture is 1 part(s) Acrylic floor wax/glue and 3 parts water. NOt sure about the proportions, you may want to check at a local pool store.
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